Journal of the American Chemical Society p. 266 - 274 (1992)
Update date:2022-08-04
Topics:
Huisgen, Rolf
Penelle, Jacques
Mloston, Grzegorz
Padias, Anne Buyle
Hall Jr.
2,2,4,4-Tetramethyl-3-thioxocyclobutanone 5-methylide (TTCM) is a nucleophilic 1,3-dipole which is known to undergo two-step cycloadditions to very electron poor olefins. When this 1,3-dipole is generated from its precursor, the 1,3,4-thiadiazoline 7, in
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