Can polymerization trap intermediates in 1,3-dipolar cycloadditions?

DOI: 10.1021/ja00027a035

Source and publish data:

Journal of the American Chemical Society p. 266 - 274 (1992)

Update date:2022-08-04

Topics:

Authors:

Huisgen, Rolf

Penelle, Jacques

Mloston, Grzegorz

Padias, Anne Buyle

Hall Jr.

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Article abstract of DOI:10.1021/ja00027a035

2,2,4,4-Tetramethyl-3-thioxocyclobutanone 5-methylide (TTCM) is a nucleophilic 1,3-dipole which is known to undergo two-step cycloadditions to very electron poor olefins. When this 1,3-dipole is generated from its precursor, the 1,3,4-thiadiazoline 7, in

Full text of DOI:10.1021/ja00027a035

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Product name:5-Thia-10-azaspiro[3.6]decane-8-carboxylic acid, 1,1,3,3-tetramethyl-2,9-dioxo-7-phenyl-, methyl ester, cis-

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