Tetrahedron Asymmetry p. 779 - 780 (1991)
Update date:2022-08-05
Topics:
Koever, Andreas
Schottelius, Thilo
Hoffmann, H. Martin R.
With zinc dust in aq.NH4Cl/THF, myrtenyl bromide (1) reacts with aldehydes (2) to give simple new pinene alcohols (β-pinene-3-yl carbinols) (3), which are enantiomerically pure (100percent de).The configuration of the new chiral centre at C-11 was determined by oxidation to the ketone 4 and stereoselective reduction to Cram alcohol 3.
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(2012)Doi:10.1039/c39910001151
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(1975)
