Synthesis of (+)-fragolide and (-)-pereniporin B via vinylsilane terminated cationic cyclization

Article abstract of DOI:10.1016/S0040-4039(00)92273-1

Enantioselective syntheses of (+)-fragolide and (-)-pereniporin B are detailed. Marino's lactone annulation method was employed to establish relative and absolute stereochemistry at carbon in the bicyclization substrate. Regio- and stereoselective oxidati