Tetrahedron Letters p. 4249 - 4250 (1991)
Update date:2022-07-31
Topics:
Chenevert, Robert
Desjardins, Michel
Both enantiomers of baclofen have been synthesized in five steps from 4-chlorocinnamic acid. The key step is the highly stereoselective enzymatic hydrolysis of dimethyl 3-(4-chlorophenyl)glutarate by chymotrypsin.
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