Evidence of stereoelectronic control in osmium-catalyzed cis-dihydroxylations of sterically unbiased 3,3-diarylcyclopentenes

DOI: 10.1021/ja00029a029

Source and publish data:

Journal of the American Chemical Society p. 980 - 985 (1992)

Update date:2022-08-06

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Authors:

Halterman, Ronald L.

McEvoy, Marjorie A.

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Article abstract of DOI:10.1021/ja00029a029

This study provides strong evidence for the stereoelectronic control of diastereoselectivity in the osmium tetraoxide-catalyzed cis-dihydroxylation of sterically unbiased 3-(4-X-phenyl)-3-phenylcyclopentenes 1 (X = NO₂, Br, Cl, OCH₃,

Full text of DOI:10.1021/ja00029a029

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