Organic and Biomolecular Chemistry p. 9288 - 9292 (2017)
Update date:2022-08-05
Topics:
Liu, Shuai
Zu, Weisai
Zhang, Jinli
Xu, Liang
Chemoselective N-arylation of unprotected aminobenzamides was achieved via Cu-catalysed Chan-Evans-Lam cross-coupling with aryl boronic acids for the first time. Simple copper catalysts enable the selective arylation of amino groups in ortho/meta/para-aminobenzamides under open-flask conditions. The reactions were scalable and compatible with a wide range of functional groups.
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