Organometallics p. 980 - 983 (1992)
Update date:2022-08-03
Topics: Chiral Cyclopentadienyl Migratory insertion CO2
Colletti, Steven L.
Halterman, Ronald L.
The migratory insertion reaction of a (cyclopentadienyl)methyliron dicarbonyl 2 containing the chiral (binaphthyldiyldimethylene)cyclopentadienyl ligand 1 in the presence of triphenylphosphine can proceed with modest diastereoselectivity. The resulting acyliron complexes 5 are separable and are configurationally stable under oxidative conditions.
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Doi:10.1021/co300023b
(2012)Doi:10.1021/acs.inorgchem.6b00586
(2016)Doi:10.1039/c2ob25360g
(2012)Doi:10.1021/ja302222s
(2012)Doi:10.1002/poc.3064
(2013)Doi:10.1039/c2dt30417a
(2012)
