Asymmetric migratory insertion reactions of the chiral [(binaphthyldiyldimethylene)cyclopentadienyl]iron complex (BpDMCp)Fe(CO)2CH3

DOI: 10.1021/om00038a076

Source and publish data:

Organometallics p. 980 - 983 (1992)

Update date:2022-08-03

Topics: Chiral Cyclopentadienyl Migratory insertion CO₂

Authors:

Colletti, Steven L.

Halterman, Ronald L.

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Article abstract of DOI:10.1021/om00038a076

The migratory insertion reaction of a (cyclopentadienyl)methyliron dicarbonyl 2 containing the chiral (binaphthyldiyldimethylene)cyclopentadienyl ligand 1 in the presence of triphenylphosphine can proceed with modest diastereoselectivity. The resulting acyliron complexes 5 are separable and are configurationally stable under oxidative conditions.

Full text of DOI:10.1021/om00038a076

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Product name:(S,S)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron

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