Tetrahedron Letters p. 6533 - 6536 (1991)
Update date:2022-08-05
Topics:
Lee, Nam Ho
Jacobsen, Eric N.
Asymmetric epoxidation of conjugated dienes and enynes catalyzed by (salen)Mn(II) coplex I takes place with high chemoselectivity to afford monoepoxides exclusively.Reactions of cis-enynes proceed with very high levels of asymmetric induction, with trans-alkynyl epoxides as the major products.
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(1991)Doi:10.1021/jo01349a070
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(2017)Doi:10.1021/ol3016447
(2012)
