Metallacarboranes as labile anions for ionic zirconocene olefin polymerization catalysts

DOI: 10.1021/om00039a058

Source and publish data:

Organometallics p. 1413 - 1416 (1992)

Update date:2022-08-05

Topics:

Authors:

Hlatky, Gregory G.

Eckman, Richard R.

Turner, Howard W.

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Article abstract of DOI:10.1021/om00039a058

Anions of the type [(C₂B₉H₁₁)₂M]^- (M = Fe, Co, Ni) are suitable for use as "noncoordinating" anions with [Cp₂ZrMe]⁺ cations. Catalysts generated from Cp₂ZrMe_{2
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Full text of DOI:10.1021/om00039a058

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Product name:(C₅H₅)2ZrCH₃(N(CH₃)2C₆H₅)⁽¹⁺⁾*{(C₂B₉H₁₁)2Co}^(1-)={(C₅H₅)2ZrCH₃(N(CH₃)2C₆H₅)}{(C₂B₉H₁₁)2Co}

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