Ready formation of stable cationic Rh(I) complexes of MeCN, formamide, urea and related species via replacement of the triflate in trans-(Ph3P)2Rh(CO)(OTf)

DOI: 10.1016/S0020-1693(00)80926-3

Source and publish data:

Inorganica Chimica Acta p. 107 - 111 (1991)

Update date:2022-09-26

Topics:

Authors:

Song, Linsheng

Stang, Peter J.

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Article abstract of DOI:10.1016/S0020-1693(00)80926-3

The weakly-coordinated trifluoromethanesulfonate (triflate) in trans-(Ph₃P)₂Rh(CO)(OTf) (OTfOSO₂CF₃) can be readily replaced by ligand L to form stable ionic complexes [trans-(Ph₃P)₂RhL(CO)

Full text of DOI:10.1016/S0020-1693(00)80926-3

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Product name:trans-{(Ph₃P)2Rh(CO)(N,N-dimethylformamide)} trifluoromethanesulfonate

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