Synthesis of (4S,5R)-(-)-4-Methyl-5-phenyloxazolidine-2-selone: A Chiral Auxiliary Reagent Capable of Detecting the Enantiomers of (R,S)-Lipoic Acid by 77Se Nuclear Magnetic Resonance Spectroscopy

DOI: 10.1039/P19910002495

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2495 - 2498 (1991)

Update date:2022-08-03

Topics:

Authors:

Silks, Louis A.

Peng, Jie

Odom, Jerome D.

Dunlap, R. Bruce

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Article abstract of DOI:10.1039/P19910002495

(4S,5R)-(-)-4-Methyl-5-phenyloxazolidine-2-selone was constructed in 5 steps on the 10-gram scale. 77Se NMR spectroscopic studies revealed that this selone served as a remarkably sensitive chiral auxiliary agent which readily distinguished the selone-coup

Full text of DOI:10.1039/P19910002495

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