Preparation and reaction of cyclic oxalate of diols

Article abstract of DOI:10.1080/00397919108021596

Cyclic oxalates were efficiently prepared by the reaction of diols with ethyl oxalyl chloride in the presence of triethylamine. They were stable under acidic conditions but cleaved to diols under basic conditions.

Full text of DOI:10.1080/00397919108021596

This article was downloaded by: [BIBLIOTHEK der Hochschule
Darmstadt]
On: 24 November 2014, At: 08:04
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number:
1072954 Registered office: Mortimer House, 37-41 Mortimer Street,
London W1T 3JH, UK
Synthetic Communications:
An International Journal
for Rapid Communication of
Synthetic Organic Chemistry
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/lsyc20
Preparation and Reaction of
Cyclic Oxalate of Diols
Kwan Soo Kim a , Eun Young Hurh a , Kyutae Na a
& Dai-Il Chung a b
a Department of Chemistry , Yonsei University ,
Seoul, 120-749, Korea
b Department of Chemistry , Dong-a University ,
Pusan, Korea
Published online: 23 Sep 2006.
To cite this article: Kwan Soo Kim , Eun Young Hurh , Kyutae Na & Dai-Il
Chung (1991) Preparation and Reaction of Cyclic Oxalate of Diols, Synthetic
Communications: An International Journal for Rapid Communication of Synthetic
Organic Chemistry, 21:22, 2361-2367, DOI: 10.1080/00397919108021596
To link to this article: http://dx.doi.org/10.1080/00397919108021596
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all
the information (the “Content”) contained in the publications on our
platform. However, Taylor & Francis, our agents, and our licensors
make no representations or warranties whatsoever as to the accuracy,
completeness, or suitability for any purpose of the Content. Any opinions
and views expressed in this publication are the opinions and views of
the authors, and are not the views of or endorsed by Taylor & Francis.

The accuracy of the Content should not be relied upon and should be
independently verified with primary sources of information. Taylor and
Francis shall not be liable for any losses, actions, claims, proceedings,
demands, costs, expenses, damages, and other liabilities whatsoever
or howsoever caused arising directly or indirectly in connection with, in
relation to or arising out of the use of the Content.
This article may be used for research, teaching, and private study
purposes. Any substantial or systematic reproduction, redistribution,
reselling, loan, sub-licensing, systematic supply, or distribution in any
form to anyone is expressly forbidden. Terms & Conditions of access
and use can be found at http://www.tandfonline.com/page/terms-and-
conditions