Synthetic Communications p. 2317 - 2327 (1991)
Update date:2022-08-04
Topics:
Barbier
Pyridine-2 or 4-carboxaldehyde,furan-2-aldehyde, were condensed on 2-coumaranone and on 5-hydroxy 2-coumaranone to give new ene-lactones analogues of the natural marginalin. Only the addition compounds issued from 2-coumaranone could give stilbene methyl esters and no rearrangement into benzo[b]furan carboxylates could be observed. These observations are discussed in relation with previous results in the series.
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