Enantioselective construction of highly functionalized bicyclo[4.3.0] system through Diels-Alder cycloaddition

DOI: 10.1016/S0957-4166(00)80029-4

Source and publish data:

Tetrahedron Asymmetry p. 1319 - 1327 (1991)

Update date:2022-07-30

Topics:

Authors:

Fuji Fuji

Tanaka Tanaka

Abe Abe

Itoh Itoh

Node Node

Taga Taga

Miwa Miwa

Shiro Shiro

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Article abstract of DOI:10.1016/S0957-4166(00)80029-4

The Diels-Alder reaction of chiral 2-alkylsulfinyl-1-nitroalkene 4 with Danishefsky's diene afforded adducts 9a and 10a in good chemical yield with a high enantiomeric excess, while diastereomeric nitroalkene 5 gave 9b and 10b, enantiomeric to 9a and 10a,

Full text of DOI:10.1016/S0957-4166(00)80029-4

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