Efficient pinacol rearrangement mediated by trimethyl orthoformate

DOI: 10.1016/S0040-4039(97)10210-6

Source and publish data:

Tetrahedron Letters p. 8315 - 8318 (1997)

Update date:2022-08-05

Topics: Experimental conditions Mediated

Authors:

Kita, Yasuyuki

Yoshida, Yutaka

Mihara, Sachiko

Fang, Dai-Fei

Higuchi, Kazuhiro

Furukawa, Akihiro

Fujioka, Hiromichi

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Article abstract of DOI:10.1016/S0040-4039(97)10210-6

An efficient pinacol rearrangment mediated by trimethyl orthoformate has been developed. The reactions of various types of diols with catalytic amount of a Lewis acid in the presence of an ortho eater afforded the rearranged product in good yields via a cyclic ortho ester intermediate.

Full text of DOI:10.1016/S0040-4039(97)10210-6

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