Journal of Organometallic Chemistry p. C9 - C12 (1992)
Update date:2022-07-30
Topics:
Uemura, Sakae
Takahashi, Hidetaka
Ohe, Kouichi
In sharp contrast to the expected formation of a telluride-palladium complex, the treatment of either (E,E)- and (Z,Z)-distyryl tellurides (1 and 2) or (E)- and (Z)-styryl phenyl tellurides (5 and 6) with Li2PdCl4 in acetonitrile at 25 deg C results in the formation of stereoisomeric 1,4-diphenylbuta-1,3-dienes, whereas the treatment of 1 and 2 with Pd(OAc)2 produces styryl acetates solely or mainly.
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