Stereo- and Regio-controlled Carbon-Carbon Bond Formation Mediated by Tungsten in the s-trans-η4-Diene Cationic Intermediates

DOI: 10.1039/c39920000045

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 45 - 46 (1992)

Update date:2022-08-03

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Authors:

Cheng, Ming-Huei

Ho, Yuung-Hsing

Wang, Sue-Lein

Cheng, Chih-Yi

Peng, Shie-Ming

et al. et al.

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Article abstract of DOI:10.1039/c39920000045

The tungsten-η³-2-substituted pentadienyl complexes WC5H5(CO)2(syn-η³-2-R-C5H6) (R = COOMe; CMe=CH2) undergo BF3-catalysed stereoselective carbon-carbon bond formation with aldehydes to afford isolable s-trans-diene cations which aft

Full text of DOI:10.1039/c39920000045

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