Electrochemical Investigations of High-Spin (10,20-Diaryletioporphyrinato II) Iron(III) Complexes

Article abstract of DOI:10.1246/bcsj.65.23

The redox behaviors of high-spin (10,20-diaryletioporphyrinato II) iron(III) complexes were investigated by cyclic voltammetry in both anodic and cathodic regions in dichloromethane.Whether the redox waves are due to a porphyrin-ring-centered reaction or a metal-centered reaction was examined in terms of the spectroelectrochemical results and Hammett reaction constants.