Bulletin of the Chemical Society of Japan p. 23 - 28 (1992)
Update date:2022-09-26
Topics:
Kijima, Masashi
Akimoto, Kei
Sakawaki, Akira
Sato, Takeo
The redox behaviors of high-spin (10,20-diaryletioporphyrinato II) iron(III) complexes were investigated by cyclic voltammetry in both anodic and cathodic regions in dichloromethane.Whether the redox waves are due to a porphyrin-ring-centered reaction or a metal-centered reaction was examined in terms of the spectroelectrochemical results and Hammett reaction constants.
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