Synthesis of γ-Keto-substituted Phosphinic Acids from Bis(trimethylsilyl)phosphonite and α,β-Unsaturated Ketones

DOI: 10.1016/S0040-4039(00)77722-7

Source and publish data:

Tetrahedron Letters p. 813 - 816 (1992)

Update date:2022-08-03

Topics:

Authors:

Boyd, E. Andrew

Regan, Andrew C.

James, Keith

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)77722-7

Mono- and di-substituted phosphinic acids have been synthesised in high yield by addition of silyl phosphonites to α,β-unsaturated ketones, and conveniently purified via their adamantanammonium salts. Key Words: Bis(trimethylsilyl)phosphonite (BTSP); Phosphinic Acids; 1,4 Michael-type Addition; Adamantanammonium Phosphinates.

Full text of DOI:10.1016/S0040-4039(00)77722-7

Products guided by the article

Product name:(2-Acetyl-cyclohexyl)-phosphinic acid

Cas No:140399-85-5

R&D Labs maybe for 140399-85-5

Shanxi Sanwei Group Co.,Ltd

Contact:0086-357-6662688

Address:Zhaocheng town, Hongtong County, Linfen City, Shanxi Province
Xuzhou Tianrun Chemical Co.,Ltd

website:http://www.tianrunchem.cn

Contact:86-516-83832636

Address:fuxing road
Huangshan Honghui Pharm Technology Co., Ltd.(expird)

website:http://www.honghuichem.com

Contact:18855958372

Address:Qingshan Wan No.1,Nanyuan Kou,SheXian Huangshan City,Anhui Province
Shanghai Sungo Technology Chemical Co., Ltd

Contact:0086-21-51385579

Address:Room2010, F/20, Tonghua Plaza, NO 345 Jinxiang Road, Jinqiao Export Processing Zone, Shanghai, 201206 P.R.CHINA
Hubei Onward Bio-Development Co., Ltd.

Contact:+86-718-8417012

Address:No.517,Shizhou Avenue,Enshi City,Hubei Province,China,445002

Relevant to this article

Construction of two new photoluminescent coordination polymers via 5-position substituted 1,3-benzenedicarboxylate

Doi:10.1080/00958972.2012.731048
(2012)
Synthesis of dispiro hetero analogs of pyrrolizidine alkaloids

Doi:10.1134/S1070428012090205
()
Triphenylphosphane complexes of copper(I): Structural and ³¹P NMR investigations

Doi:10.1016/0277-5387(95)00595-1
(1996)
Synthesis of the 17-electron cations [FeL(L′)(NO)₂]⁺ (L, L′ = PPh₃, OPPh₃): Structure and bonding in four-co-ordinate metal dinitrosyls, and implications for the identity of paramagnetic iron dinitrosyl complex catalysts

Doi:10.1039/DT9960003491
(1996)
Synthesis and structure of a 2 Cu^II 2 Cu^I constellation ligated by the new biimidazole, bis(1-methyl-4,5-diphenylimidaz-2-oyl)carbinol

Doi:10.1039/cc9960000921
(1996)
Tetrahedral rigid core antenna chromophores bearing bay-substituted perylenediimides

Doi:10.1016/j.tet.2015.10.083
(2015)

Article Doi