Double Metal-Catalyzed Cross-Coupling Reactions of Alkenyl Sulfoximines with Diorganozinc Reagents: Synthesis of Optically Active Axial Chiral Allylic Silanes

DOI: 10.1016/S0040-4039(00)93968-6

Source and publish data:

Tetrahedron Letters p. 461 - 464 (1992)

Update date:2022-07-30

Topics:

Authors:

Gais, Hans-Joachim

Buelow, Gerd

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)93968-6

Nickel- and magnesium-catalyzed cross-coupling reaction of the alkenyl sulfoximine 5 with the pure diorganozinc reagents 6a and 6b gave the optically active allylic silanes 7a and 7b, respectively.Single metal catalysis was sufficient for the substitution

Full text of DOI:10.1016/S0040-4039(00)93968-6

Products guided by the article

Product name:Silane, [2-[4-(1,1-dimethylethyl)cyclohexylidene]ethyl]dimethyl(1-methylethoxy)-, (R)-

Cas No:140402-04-6

R&D Labs maybe for 140402-04-6

ZHIJIANG ZENVA SINO COMMERCE AND TRADE CO., LTD.

website:http://www.zenvasino.com

Contact:+86-138-72658998

Address:Shibeishan Road,Zhijiang, Hubei, China
Hebei Kangtai Pharmaceutical Co.,Ltd

Contact:+86-0317-3512963

Address:Wugang Road,Mengcun of Cangzhou City,Hebei Province ,China
Changzhou Qidi Chemical Co., Ltd

website:http://www.czqdhg.com/

Contact:86-519-83382137

Address:128-1-16# HuaYuan Street,Hutang Town,Wujin District,Changzhou City,P.R.China.
Shanghai WinTide BioTechnology Co.,Ltd

Contact:86-21-37100630

Address:No. 908 Yunhe Road, Fengxian district, Shanghai
Chongqing Rong＆Quan Pharmaceutical Technology Co. , Ltd.

Contact:86-023-65268721

Address:No. 7, Manshanhong Village, Pingdingshan, Shapingba District, Chongqing Province, China

Relevant to this article

Hydrogen-bonding thiourea organocatalysts: The privileged 3,5-bis(trifluoromethyl)phenyl group

Doi:10.1002/ejoc.201200739
(2012)
Synthesis and anti-influenza a virus activity of 2,2-dialkylamantadines and related compounds

Doi:10.1021/ml300279b
(2012)
Donor-π-acceptors containing the 10-(1,3-dithiol-2-ylidene)anthracene unit for dye-sensitized solar cells

Doi:10.1002/chem.201201022
(2012)
Synthesis and structural characterization of new cu(I) complexes with the antithyroid drug 6-n-propyl-thiouracil. Study of the cu(I)-catalyzed intermolecular cycloaddition of iodonium ylides toward benzo[b]furans with pharmaceutical implementations

Doi:10.1021/ic3014255
(2012)
The total syntheses of (±)-α- and β-dihydrocleavamines, (±)-16-methoxycarbonyldihydrocleavamine (±)-coronaridine, (±)-dihydrocatharanthine, (±)-ibogamine, (±)-epi-ibogamine and (±)-catharanthine

Doi:10.1016/0040-4020(80)80061-5
(1980)
An efficient catalytic deprotection of thioacetals employing bismuth triflate: Synthesis of pyrrolo[2,1-c] [1,4] benzodiazepines

Doi:10.1016/S0040-4039(03)00437-4
(2003)

Article Doi