Double Metal-Catalyzed Cross-Coupling Reactions of Alkenyl Sulfoximines with Diorganozinc Reagents: Synthesis of Optically Active Axial Chiral Allylic Silanes

DOI: 10.1016/S0040-4039(00)93968-6

Source and publish data:

Tetrahedron Letters p. 461 - 464 (1992)

Update date:2022-07-30

Topics:

Authors:

Gais, Hans-Joachim

Buelow, Gerd

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Article abstract of DOI:10.1016/S0040-4039(00)93968-6

Nickel- and magnesium-catalyzed cross-coupling reaction of the alkenyl sulfoximine 5 with the pure diorganozinc reagents 6a and 6b gave the optically active allylic silanes 7a and 7b, respectively.Single metal catalysis was sufficient for the substitution

Full text of DOI:10.1016/S0040-4039(00)93968-6

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