Selective formation of either Tr?ger's base or spiro Tr?ger's base derivatives from [2-aminoporphyrinato(2-)]nickel by choice of reaction conditions

DOI: 10.1016/j.tetlet.2012.08.097

Source and publish data:

Tetrahedron Letters p. 6015 - 6017 (2012)

Update date:2022-07-29

Topics:

Authors:

Tatar, Ameneh

Dolensky, Bohumil

Dvo?áková, Hana

Král, Vladimír

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Article abstract of DOI:10.1016/j.tetlet.2012.08.097

The article reports on the unique manipulation of the acid-catalyzed reaction of [2-aminoporphyrinato(2-)]nickel with formaldehyde to form selectively either the symmetric Tr?ger's base or the asymmetric spiro Tr?ger's base bis(metalloporphyrin) derivativ

Full text of DOI:10.1016/j.tetlet.2012.08.097

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