Palladium-catalysed Polycyclization of Dienynes to give Carbocyclic angularly Bisanellated Cyclohexadiene Derivatives

DOI: 10.1039/c39920000390

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 390 - 392 (1992)

Update date:2022-08-05

Topics:

Authors:

Meyer, Frank E.

Brandenburg, Joerg

Parsons, Philip J.

Meijere, Armin de

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Article abstract of DOI:10.1039/c39920000390

Various 2-bromododeca-1,11-dien-6-ynes 1a,b,8 and trans- or cis-10a,b when subjected to Heck reaction conditions, cleanly undergo palladium-catalysed biscyclizations followed by an electrocyclic rearrangement to form tricyclic cyclohexadienes 5a,b,9 and cis- or trans-11a,b as sole products (7 examples).

Full text of DOI:10.1039/c39920000390

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