Journal of the Chemical Society. Chemical communications p. 415 - 416 (1992)
Update date:2022-07-31
Topics:
Guillemin, Jean-Claude
Janati, Tajdine
Denis, Jean-Marc
Phosphaalkynes bearing primary carbon substituents are prepared in good yield by low-temperature Lewis base-induced rearrangement of primary ethyn-1-ylphosphines; the mechanism involves a P-unsubstituted phosphaallene intermediate.
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Doi:10.1016/S0040-4039(00)91731-3
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