1,5-Asymmetric induction in reactions of δ-alkoxyallylstannanes: Stereoselective reactions with chiral aldehydes

Article abstract of DOI:10.1016/S0040-4039(00)91625-3

Transmetallation of (4S,2E)-4-phenylmethoxypent-2-enyl(tributyl)stannane 1 using tin(IV)chloride generates a reagent which shows excellent 1 5-stereoselectivity in reactions with aldehydes: with chiral aldehydes, the stereochemical preference of the reage