Reaction of cycloalkylphosphorane with perfluoroalkylnitrile: A new synthesis of some fluorine-containing cyclic 1,3-diketones and oxo esters

Article abstract of DOI:10.1055/s-1992-26099

The preparation of some new perfluoroalkyl 1,3-dicarbonyl compounds is reported. The alcoholysis reaction of these 2-perfluoroalkanoylcycloalkanones in the presence or in the absence of base catalysis occurs, involving ring cleavage to yield fluorinated o