Tetrahedron Letters p. 899 - 902 (1992)
Update date:2022-07-30
Topics: Oxidation Asymmetric synthesis Yield NMR spectroscopy Mass spectrometry Solvent Reduction Enantiomeric excess (ee) Chromatography Precursor Alkaloid Protecting group Retrosynthetic analysis Catalysis Coupling Reaction Indole Reaction Optimization Stereospecific synthesis Vinblastine
Magnus, Philip
Mendoza, Jose
The stereospecific synthesis of a precursor to the top-half of vinblastine is described.Its non-oxidative coupling to m-methoxy-N,N-dimethylaniline provides access to the vinblastine analogue 18.
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