Chemistry Letters p. 687 - 690 (1992)
Update date:2022-08-02
Topics: Asymmetric synthesis Column chromatography Yield NMR spectroscopy Stereochemistry Enantioselectivity Recrystallization Catalytic hydrogenation Total synthesis Mass spectrometry (MS) Optical rotation TLC (thin-layer chromatography) Protecting group Retrosynthetic analysis Reaction Monitoring Chiral Pool Antibiotic
Chida, Noritaka
Yamada, Ken
Ogawa, Seiichiro
The stereoselective conversion of naturally occurring optically active cyclitol, L-quebrachitol (2), into antifungal (E)-β-methoxyacrylate, oudemansin X is described.This synthesis fully confirmed the proposed absolute configuration of the antibiotic and
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(1992)
