Angewandte Chemie - International Edition p. 9547 - 9551 (2012)
Update date:2022-08-04
Topics:
Weng, Yue
Cheng, Ben
He, Chuan
Lei, Aiwen
Less is More: A highly selective Pd-catalyzed Csp-Csp cross-coupling reaction between terminal alkynes and 1-bromoacetylenes has been developed. Catalyst loading is low (only 0.0001-0.01 mol % of Pd is required) and provides products with high selectivities and good to excellent yields under mild conditions. TBAB=tetrabutylammonium bromide, TON=turnover number. Copyright
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