New Catecholato Oxorhenium(V) Complexes

DOI: 10.1039/DT9920000957

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 957 - 962 (1992)

Update date:2022-08-04

Topics:

Authors:

Edwards, Catherine F.

Griffith, William P.

White, Andrew J. P.

Williams, David J.

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Article abstract of DOI:10.1039/DT9920000957

The complexes , n4>(L' = OPPh3, MeOH or pyridine), n4> and I have been isolated and their infrared, Raman, (31)P and (13)C NMR spectra are reported.The X-ray crystal structures of n4> 1 and n4> 2 are presented.In both molecules the co-ordination geometry about Re is very similar, being distorted octahedral with the catcholato ligands folded away from a very strongly bonded oxo ligand <1.576(8) Angstroem in 1 and 1.653(11) Angstroem in 2> with weakly bound OPPh3 and MeOH ligands and MeOH ligands in the trans positions.

Full text of DOI:10.1039/DT9920000957

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