Journal of the American Chemical Society p. 11906 - 11913 (1995)
Update date:2022-09-26
Topics:
Coolen, Hein K. A. C.
Meeuwis, Johannes A. M.
Van Leeuwen, Piet W. N. M.
Nolte, Roeland J. M.
A novel supramolecular catalyst functioning according to the principles of enzymatic catalysis is described. It consists of a basket-shaped molecule to which a catalytically active Rh(I) complex is attached. The catalyst selectively hydrogenates and isomerizes allyl-substituted dihydroxyarene substrates that are bound in its cavity. The reactivity of this supramolecular catalyst and its affinity for several substrates is compared with that of the corresponding catalyst without a binding site. Features known from enzymatic catalysis, e.g. Michaelis-Menten kinetics and rate enhancement by cooperative binding, are described and discussed.
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