Syntheses and Structures of , , (L = N2 or CO) and

DOI: 10.1039/DT9950003153

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3153 - 3164 (1995)

Update date:2022-08-02

Topics:

Authors:

Dilworth, Jonathan R.

Hu, Jin Hu, Jin

Miller, John R.

Hughes, David L.

Zubieta, Jon A.

Chen, Qin

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Article abstract of DOI:10.1039/DT9950003153

The hydride reacted with 2,6-dimethylbenzenethiol in toluene to give a complex of stoichiometry 1.A crystal structure showed a trigonal-bipyramidal geometry about the Re with an agostic interaction to a thiolate methyl occupying an apical site, trans to the PPh3 ligand.Complex 1 reacts rapidly with MeCN to give the known 2 and with t-BuNC to form 3.The crystal structure of 3 showed trigonal-pyramidal geometry about the Re with asymmetric co-ordination of the isocyanide ligands and an unusual configuration for the thiolate aromatic groups.The reactions of the hydrides and with 2,4,6-triisopropyl-, 2,6-dimethoxy-benzenethiol and tris(2-sulfanylphenyl)phosphine were also studied.With HSC6H2(i-Pr)3-2,4,6 the dinitrogen complex 4 was formed and its structure determined.The preparations and structures of the complexes , 3(PPh3)> and (PPh3)> are also discussed.An alternative convenient route to (+) from is presented.

Full text of DOI:10.1039/DT9950003153

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