Tetrahedron Letters p. 639 - 642 (1992)
Update date:2022-08-05
Topics:
Oishi, Tohru
Hirama, Masahiro
Chiral 2,3-disubstituted 1,4-diazabicyclo[2.2.2]octane (DABCO) derivatives have been synthesized and utilized as a chiral ligand for the osmium-catalyzed asymmetric dihydroxylation of olefins. Optically active diols in up to 41%ee are obtained in good yields.
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