Journal of the Chemical Society. Chemical communications p. 119 - 120 (1995)
Update date:2022-08-05
Topics:
Allen, Christopher C. R.
Boyd, Derek R.
Dalton, Howard
Sharma, Narain D.
Haughey, Simon A.
et al.
Selected strains of the bacterium Pseudomonas putida (previously shown to effect dioxygenase-catalysed asymmetric cis-dihydroxylation of alkenes) have been found to yield chiral sulfoxides from the corresponding sulfides with a strong preference for the (R)- or (S)-configurations but without evidence of sulfone formation; similar results obtained using an Escherichia coli clone (pKST11, containing the Tod C1 C2 B and A genes encoding toluene dioxygenase from P. putida NCIMB 11767) are again consistent with a stereoselective dioxygenase-catalysed sulfoxidation.
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