Journal of Organic Chemistry p. 5766 - 5768 (2003)
Update date:2022-08-03
Topics:
Nakamura, Shuichi
Nakayama, Jun-ichi
Toru, Takeshi
The reaction of the α-carbanion of p-tolyl 2-(trimethylsilyl)ethyl sulfoxide with esters followed by reduction with DIBAL gave α-(trimethylsilyl)methyl-β-hydroxysulfoxides with high stereoselectivity. The stereoselective reaction was demonstrated to proceed through a dynamic kinetic resolution pathway via a six-membered cyclic transition state involving Si-O interaction. These reactions provide a convenient route for the synthesis of optically pure allylic alcohols.
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Doi:10.1039/c3cc00196b
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