Organic Mass Spectrometry p. 589 - 596 (1992)
Update date:2022-08-04
Topics:
Lefevre, O.
Mollova, N.
Longevialle, P.
Large-ring cycloalkylamines rearrange after electron impact ionization into long-chain enamines.A general mechanism is proposed for their fragmentation, and a parallel is established with the fragmentation of long-chain esters (lipids).It is shown that the parent ions rearrange into a series of interconverting branched onium ions from which alkyl radicals are lost.The mechanism of the interconversion is discussed.
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