Diastereoselective synthesis of enantiopure γ-butenolide- butyrolactones towards Pseudopterogorgia lactone furanocembranoid substructures

DOI: 10.1055/s-0032-1317555

Source and publish data:

Synlett p. 2909 - 2912 (2012)

Update date:2022-07-30

Topics:

Authors:

MacAbeo, Allan Patrick G.

Lehmann, Christian W.

Reiser, Oliver

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Article abstract of DOI:10.1055/s-0032-1317555

A diastereoselective methodology for preparing trans-γ-lactone- γ-butenolides through vinylogous aldol additions of siloxyfuranes to enantiopure cyclopropylcarbaldehyde followed by a tin-catalyzed retroaldol-lactonization cascade is reported. This synthet

Full text of DOI:10.1055/s-0032-1317555

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