Arene 1,4-diradical formation from o-dialkynylarenes

DOI: 10.1016/S0040-4039(00)92066-5

Source and publish data:

Tetrahedron Letters p. 3277 - 3280 (1992)

Update date:2022-08-05

Topics: Kinetic studies Reaction Conditions Spectroscopic Analysis Arene

Authors:

Semmelhack

Neu, Thomas

Foubelo, Francisco

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)92066-5

A series of five arene and quinone derivatives with dialkynyl substituents in the ortho positions and fixed in a 10-membered ring were prepared and tested with respect to thermal rearrangement to the corresponding arene 1,4 diradicals.

Full text of DOI:10.1016/S0040-4039(00)92066-5

Products guided by the article

Product name:1,2,3,4-Tetrahydro-7,12-pentacenequinone

Cas No:142672-74-0

R&D Labs maybe for 142672-74-0

uni source industries limited

Contact:86 21 3772 9386

Address:Rm.1803,Starry Bldg.1,1505 Meijiabang Road,Shanghai 201620 China
Beijing Tianjia Chemical Science & Technology Co.,Ltd

Contact:86-0550-2392698

Address:No.388, Shiliang Road (East),
Qingdao Pana-Life Biochem Co.,Ltd.

Contact:86-532-87683902

Address:No.967 Dalao Road, Licang Zone, Qingdao City,Shandong, China 266021
Changzhou Sunlight Pharmaceutical Co., Ltd.

Contact:+86-519-83131668;83139028;83138042;83137041

Address:JiuliStreet, Benniu Town Changzhou City, Jiangsu Province
SHANDONG CREDAGRI CHEMICAL CO., LTD.

Contact:+86-531-88872050

Address:ROOM 601A, BUILDING 2, SHUNTAI SQUARE, NO. 2000 SHUNHUA ROAD, HI-TECH DEVELOPMENT ZONE, JINAN, CHINA.

Relevant to this article

Synthesis of gem-difluoromethylenated spiro-γ-butyrolactones by employing PhSCF₂Si(CH₃)₃ as a gem-difluoromethylenating agent

Doi:10.1002/ejoc.201300998
(2013)
Copper-catalyzed aldol-type addition of ketones to aromatic nitriles: A simple approach to enaminone synthesis

Doi:10.1039/c3cc40466h
(2013)
A dual arylboronic acid-aminothiourea catalytic system for the asymmetric intramolecular hetero-michael reaction of α,β-unsaturated carboxylic acids

Doi:10.1021/ol501954r
(2014)
Bicyclo[3.3.1]nonane approach to triquinanes. Formal synthesis of (+/-)Δ(9(12))capnellene and [+/-)Δ(9(12))capnellene-8-β-10α-diol

Doi:10.1016/S0040-4020(01)80453-1
(1992)
On the importance of intermolecular interactions of 3-(2,3-dihydroxy-isopentyl)-4-hydroxyacetophenone: Crystal structure, spectroscopic and hirshfeld surface analysis

Doi:10.1016/j.molstruc.2020.128393
(2020)
Doi:10.1039/j39670000189
(1967)

Article Doi