Solar-driven incorporation of carbon dioxide into α-amino ketones

DOI: 10.1002/anie.201206166

Source and publish data:

Angewandte Chemie - International Edition p. 11750 - 11752 (2012)

Update date:2022-08-05

Topics: Catalyst PHOTOCHEMICAL REACTION Product Carbon Dioxide Experimental terms Reactant Incorporation α-amino ketones

Authors:

Ishida, Naoki

Shimamoto, Yasuhiro

Murakami, Masahiro

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Article abstract of DOI:10.1002/anie.201206166

Power of the sun: Carbon dioxide was incorporated into α-amino ketones through a consecutive process consisting of a solar-energy-harvesting photocyclization reaction and a nucleophilic CO₂ incorporation reaction. The single-flask operation produced amino-substituted cyclic carbonates, thereby presenting a simple model of the chemical utilization of solar energy for CO₂ incorporation. R=sulfonyl group. Copyright

Full text of DOI:10.1002/anie.201206166

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