Unusual Behaviour of Some γ- and δ-Lactones Towards Dichloromethylenation using Tris(dimethylamino)phosphine-Tetrachloromethane

DOI: 10.1039/P19920001471

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1471 - 1474 (1992)

Update date:2022-09-26

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Authors:

Bandzouzi, Alphonse

Lakhrissi, Mohammed

Chapleur, Yves

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Article abstract of DOI:10.1039/P19920001471

Lactones derived from D-glucose, D-mannose and L-ascorbic acid reacted unexpectedly with tris(dimethylamino)phosphine-tetrachloromethane to give, respectively, dichloroalkene, anomeric vinyl chloride or acyl chloride; this behaviour supports an ionic mech

Full text of DOI:10.1039/P19920001471

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