Stereoselective aminohomologation of chiral α-alkoxy aldehydes via thiazole addition to nitrones. Application to the synthesis of N-acetyl-D-mannosamine

DOI: 10.1016/S0040-4039(00)74694-6

Source and publish data:

Tetrahedron Letters p. 4221 - 4224 (1992)

Update date:2022-08-03

Topics:

Authors:

Dondoni Dondoni

Junquera

Merchan Merchan

Merino Merino

Tejero Tejero

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Article abstract of DOI:10.1016/S0040-4039(00)74694-6

The addition of 2-lithiothiazole to nitrones derived from D-glyceraldehyde and D-arabinose affords anti-adducts from which α-amino aldehydes are revealed by thiazole-to-formyl deblocking. The methodology provides a new synthesis of N-acetyl D-mannosamine

Full text of DOI:10.1016/S0040-4039(00)74694-6

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