Facile Chlorination of Sugar Moiety of Nucleosides by Use of Tris(2,4,6-tribromophenoxy)dichlorophosphorane

DOI: 10.1246/cl.1992.1505

Source and publish data:

Chemistry Letters p. 1505 - 1506 (1992)

Update date:2022-08-03

Topics: Yield Solvent Chlorination Stirring Filtration Nucleosides Sugar moiety Facile Reaction Vessel Reactant

Authors:

Ohuchi, Shokichi

Singh, Ramendra K.

Wada, Takeshi

Hata, Tsujiaki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1992.1505

A versatile chlorinating reagent, tris(2,4,6-tribromophenoxy)dichlorophosphorane was applied for 5'- and 3'-chlorination of nucleosides.It was found that the reaction proceeded via S_N2 mechanism.

Full text of DOI:10.1246/cl.1992.1505

Products guided by the article

Product name:Adenosine, N-benzoyl-5'-chloro-3',5'-dideoxy-, 3'-benzoate

Cas No:143997-08-4

R&D Labs maybe for 143997-08-4

Zhengzhou Yuanli Biological Technology Co., Ltd.

Contact:+86-371-67897870/67897895

Address:No. 38, Qingyang Street, Zhengzhou, Henan, China
Sinonine Industry Co.,Ltd

Contact:86+21-56421993

Address:3F,BUILDING 10,NO.2889 JINKE ROAD, SHANGHAI.
Tianjin Boron PharmaTech Co.,Ltd.(expird)

Contact:86-022-59845187

Address:B9-401, Tianda Science Park,No.80,4th Avenue,TEDA,Tianjin, China
Winchem Industrial Co. Ltd.(expird)

Contact:86-574-83851061 86-574-87083208

Address:Room 905, No.3 Building,East Business Center, 456 Xingning Road, Ningbo City,China
Shandong Dayi Chemical Co., Ltd.

website:http://www.dayi.com.cn

Contact:+86- 535-7388728. 15306386031

Address:No 1 Danya west road, Laiyang City, Shandong province

Relevant to this article

Rhodium(III) and hexabromobenzene - A catalyst system for the cross-dehydrogenative coupling of simple arenes and heterocycles with arenes bearing directing groups

Doi:10.1002/anie.201205734
()
Mono, bi- and trinuclear metal complexes derived from new benzene-1,4-bis(3-pyridin-2-ylurea) ligand. Spectral, magnetic, thermal and 3D molecular modeling studies

Doi:10.1016/j.saa.2013.03.016
(2013)
Doi:10.1016/S0022-328X(00)86330-5
(1968)
Stereochemical outcome of copper-catalyzed C-H insertion reactions. an experimental and theoretical study

Doi:10.1021/jo400415b
(2013)
AN EFFICIENT SYNTHETIC METHOD FOR OPTICALLY PURE HETEROHELICENES

Doi:10.1016/S0040-4039(00)61323-0
(1992)
Mercuric Acetate Oxidation of Avermectin A_2a as a Route to the Selective Cleavage of the Allylic C-5-Methoxy Group

Doi:10.1021/jo00365a039
(1986)

Article Doi