A New Synthesis of α-Fluoro-α,β-unsaturated Ketones and Esters based on Organoselenium Methodology

DOI: 10.1039/c39920001148

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Journal of the Chemical Society. Chemical communications p. 1148 - 1150 (1992)

Update date:2022-08-04

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Authors:

Usuki, Yoshinosuke

Iwaoka, Michio

Tomoda, Shuji

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Article abstract of DOI:10.1039/c39920001148

Fluoroselenylation of α-diazoketones and α-diazoesters using a phenylselenyl fluoride equivalent, generated in situ from phenylselenenyl bromide and AgF, followed by oxidation with hydrogen peroxide, provided α-fluoro-α,β-unsaturated ketones and ester, respectively, in moderate yields.

Full text of DOI:10.1039/c39920001148

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