Short and efficient Syntheses of (-)-Isocitric acid lactone and (-)-Homoisocitric acid. Conversion of Alkynylsilanes into the corresponding Carboxylic acids

DOI: 10.1016/S0040-4039(00)61231-5

Source and publish data:

Tetrahedron Letters p. 4911 - 4912 (1992)

Update date:2022-08-02

Topics: Carboxylic Acids

Authors:

Schmitz, Carole

Rouanet-Dreyfuss, Anne-Claire

Tueni, Marie

Biellmann, Jean-Francois

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)61231-5

We describe a simple synthesis of natural isocitric and homoisocitric acids from a common intermediate 2.A new method of conversion from a silylated triple bond to the carboxylic acid of the same chain length has been formulated.Keywords: Isocitric acid lactone; homoisocitric acid; D-malic acid; conversion of alkynylsilane to carboxylic acid

Full text of DOI:10.1016/S0040-4039(00)61231-5

Products guided by the article

Product name:methyl 2-hydroxy-3-carbomethoxy-6-(trimethylsilyl)-5-hexynoate

Cas No:144460-34-4

R&D Labs maybe for 144460-34-4

Nanjing Duly Biotech Co., Ltd

website:http://www.dulynet.com/

Contact:025-84699383 -8003

Address:Room 503, Building 2, Chuangxinhui, No. 61 Wenjing Road, High-tech Development Zone, Pukou District, Nanjing City, Jiangsu Province Nanjing, Jiangsu
Shantou Baokang Pharmaceutical Co., Ltd.

Contact:+86-754-88873487

Address:5/F B Block Huangshan Bldg Huangshan Rd Shantou
Baicao Pharmaceutical Co., Ltd.

website:http://www.jxbaicao.com

Contact:+86-796-8113329

Address:It (country) economic and technological development zone of the jinggang mountains
Sarchem Laboratories, Inc.

Contact:732.938.2777

Address:5012 Industrial Road Farmingdale, NJ 07727
JiYi Chemical (Beijing) Co., Ltd.

Contact:+86-10-89385733

Address:Shilou Town of Fangshan District， Beijing

Relevant to this article

Assessment of mycobacterium tuberculosis pantothenate kinase vulnerability through target knockdown and mechanistically diverse inhibitors

Doi:10.1128/AAC.00140-14
(2014)
Efficient synthesis of 3-substituted indoles through a domino gold(I) chloride catalyzed cycloisomerization/C3-functionalization of 2-(alkynyl)anilines

Doi:10.1016/j.tet.2009.09.019
(2009)
Asymmetric catalysis of the carbonyl-amine condensation: Kinetic resolution of primary amines

Doi:10.1021/jacs.6b12176
(2017)
Microwave-assisted synthesis of α-ethoxycarbamates

Doi:10.1016/j.tet.2009.09.023
(2009)
Synthesis of triphenylamines: Via ligand-free selective ring-opening of benzoxazoles or benzothiazoles under superparamagnetic nanoparticle catalysis

Doi:10.1039/c7ra06168d
(2017)
C-H...N hydrogen bonds mediated solid state structures of 2,2′-bis(4-pyridylsulfanylmethyl)-1,1′-biphenyl and 9-(4-pyridylsulfanyl)phenanthrene

Doi:10.1016/j.molstruc.2009.08.020
(2009)

Article Doi