Short and efficient Syntheses of (-)-Isocitric acid lactone and (-)-Homoisocitric acid. Conversion of Alkynylsilanes into the corresponding Carboxylic acids

DOI: 10.1016/S0040-4039(00)61231-5

Source and publish data:

Tetrahedron Letters p. 4911 - 4912 (1992)

Update date:2022-08-02

Topics: Carboxylic Acids

Authors:

Schmitz, Carole

Rouanet-Dreyfuss, Anne-Claire

Tueni, Marie

Biellmann, Jean-Francois

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Article abstract of DOI:10.1016/S0040-4039(00)61231-5

We describe a simple synthesis of natural isocitric and homoisocitric acids from a common intermediate 2.A new method of conversion from a silylated triple bond to the carboxylic acid of the same chain length has been formulated.Keywords: Isocitric acid lactone; homoisocitric acid; D-malic acid; conversion of alkynylsilane to carboxylic acid

Full text of DOI:10.1016/S0040-4039(00)61231-5

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