ZnBr2-catalyzed Stereospecific 1,4-Elimination of 1-Methoxymethyl-2-(trimethylsilylmethyl)cyclobutanes. Stereoselective Preparation of 1,1,5-Trisubstituted (E)- and (Z)-1,5-Dienes

DOI: 10.1246/cl.1992.1631

Source and publish data:

Chemistry Letters p. 1631 - 1634 (1992)

Update date:2022-08-05

Topics:

Authors:

Fujiwara, Tooru

Suda, Atsushi

Takeda, Takeshi

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Article abstract of DOI:10.1246/cl.1992.1631

The stereoselective addition of alkylmetals to 2-(trimethylsilylmethyl)-1-cyclobutyl ketones and the ZnBr2-catalyzed stereospecific ring-opening reaction of resulting 1-methoxymethyl-2-(trimethylsilylmethyl)cyclobutanes gave 1,1,5-trisubstituted 1,5-diene

Full text of DOI:10.1246/cl.1992.1631

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Product name:[4-(1-Methoxy-1-phenyl-ethyl)-1,2,2-trimethyl-cyclobutylmethyl]-trimethyl-silane

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