Construction of bicyclic systems via a tandem free radical cyclopropylcarbinyl rearrangement-cyclisation strategy

DOI: 10.1016/S0040-4020(01)80475-0

Source and publish data:

Tetrahedron p. 8031 - 8052 (1992)

Update date:2022-08-05

Topics:

Authors:

Batey Batey

Harling Harling

Motherwell

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Article abstract of DOI:10.1016/S0040-4020(01)80475-0

Regio- and stereospecific construction of bicyclic systems may be achieved by directed Simmons-Smith cyclopropanation of an allylic alcohol possessing a suitably positioned unsaturated acceptor, followed by a tandem free radical cyclopropylcarbinyl rearrangement-cyclisation reaction.

Full text of DOI:10.1016/S0040-4020(01)80475-0

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