Thallium(III) nitrate mediated ring contraction of 2-aryl-1,2,3,4- tetrahydro-4-quinolones: Stereoselective synthesis of trans methyl 2-aryl-2,3-dihydroindol-3-carboxylates

DOI: 10.1080/00397910500466462

Source and publish data:

Synthetic Communications p. 943 - 950 (2006)

Update date:2022-09-26

Topics:

Authors:

Singh, Om

Muthukrishnan

Sundaravedivelu

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Article abstract of DOI:10.1080/00397910500466462

The ring contraction of N-acetyl-2-aryl-1,2,3,4-tetrahydro-4-quinolones 1a-d with thallium(III) nitrate in trimethyl orthoformate afforded stereoselectively trans methyl N-acetyl-2-aryl-2,3-dihydroindol-3-carboxylates 5a-d by oxidative rearrangement of ar

Full text of DOI:10.1080/00397910500466462

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