Stereoselective construction of all-carbon quaternary stereocenters by allylboration of chiral aldehydes: synthesis of a fragment of (+)-vibsanin A

DOI: 10.1016/j.tet.2016.07.030

Source and publish data:

Tetrahedron p. 5465 - 5471 (2016)

Update date:2022-08-04

Topics:

Authors:

Sakama, Akihiro

Nishimura, Yoshiyasu

Motohashi, Yuko

Yoshida, Keisuke

Takao, Ken-ichi

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Article abstract of DOI:10.1016/j.tet.2016.07.030

Stereoselective construction of all-carbon quaternary stereocenters by allylboration of chiral aldehydes is described. Sugar-derived aldehydes were allylated with geranylboronate or nerylboronate to provide γ-adducts possessing quaternary stereocenters wi

Full text of DOI:10.1016/j.tet.2016.07.030

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