Asymmetric hydroformylation of deltacyclene

DOI: 10.1016/S0957-4166(00)86031-0

Source and publish data:

Tetrahedron Asymmetry p. 1011 - 1014 (1992)

Update date:2022-09-26

Topics:

Authors:

Kollar Kollar

Wada Wada

Lautens Lautens

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Article abstract of DOI:10.1016/S0957-4166(00)86031-0

Deltacyclene (tetracyclo[4,3,0,0^2,90^3,7]non-4-ene was stereoselectively hydroformylated to exo-formyl-deltacyclane in the presence of rhodium and platinum catalysts. In the case of optically active bisphosphines up to 22% e.e-s were achieved.

Full text of DOI:10.1016/S0957-4166(00)86031-0

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Product name:1,2,4-Methenopentalene-5-carboxaldehyde, octahydro-, [1R-(1alpha,2alpha,3abeta,4alpha,5beta,6abeta,7S*)]- (9CI)

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