Mild stereoselective syntheses of thioglycosides under PTC conditions and their use as active and latent glycosyl donors

Article abstract of DOI:10.1016/S0957-4166(00)86308-9

Mild and stereoselective arylthio glycoside syntheses were accomplished by inversion of configuration of glycosyl halides under phase transfer catalyzed conditions. Under such conditions, aryl α-thiosialosides having electron donating and withdrawing subs