Use of Hydrogen Bonds to Control Molecular Aggregation. Behavior of a Self-Complementary Dipyridone Designed to Self-Replicate

DOI: 10.1021/jo00053a020

Source and publish data:

Journal of Organic Chemistry p. 95 - 99 (1993)

Update date:2022-08-04

Topics: Enantiomer Crystallization NMR spectroscopy Chemical shift Mass spectrometry Ligand Nucleophile Electrophile Scanning electron microscopy (SEM) Transmission electron microscopy (TEM) Steric hindrance Deprotonation Chromatography Protonation Differential scanning calorimetry (DSC) Solubility binding affinity HPLC (high-performance liquid chromatography) Self-assembly Resonance Electrospray ionization (ESI) X-ray crystallography Tautomerism Chelation Density functional theory (DFT) Crystal packing UV-Vis Spectroscopy Fluorescence Spectroscopy Integration Reaction Kinetics Circular Dichroism (CD) Solvent Effects Micelle Formation Computational Modeling Catalysis Deuterium Exchange Chirality Supramolecular Chemistry Template-Directed Synthesis Molecular Recognition Conformational Analysis Activation Energy Synchrotron Radiation Thermogravimetric Analysis (TGA) Kinetic Control Thermodynamic Control Flash Photolysis Van der Waals Forces Host-Guest Chemistry Stoichiometry

Authors:

Persico, Francois

Wuest, James D.

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Article abstract of DOI:10.1021/jo00053a020

In principle, the simple dipyridone 4 encodes enough chemical information to allow it to self-replicate by acting as a template for the assembly and controlled oxidative coupling of ethynylpyridone subunits 5 and 6.This could occur by the formation of ter

Full text of DOI:10.1021/jo00053a020

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